#Copper-catalyzed enantioselective trifluoromethylation of benzylic radicals developed

“#Copper-catalyzed enantioselective trifluoromethylation of benzylic radicals developed” Credit: CC0 Public Domain Scientists from the Shanghai Institute of Organic Chemistry of the Chinese Academy of Sciences (CAS) have developed the first copper-catalyzed enantioselective trifluoromethylation of benzylic radicals via a copper-catalyzed radical relay strategy. The incorporation of trifluoromethyl (CF3) groups into biologically active molecules has a significant…

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#Epitaxial antiperovskite/perovskite heterostructures for materials design

“#Epitaxial antiperovskite/perovskite heterostructures for materials design” Schematic representation of the crystal structures of M3XN nitride antiperovskite and ABO3 oxide perovskite compounds and their interfaces. (A) M3XN and ABO3 ideal unit cells showing their geometrically analogous crystal structures and reversed anion (N and O) and cation (M and B) positions in the unit cell. (B) M3XN…

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#The varnishing point: Where science meets art

“#The varnishing point: Where science meets art” In 2014, the art conservation world was thrown into chaos when the company producing MS2A varnish shut down. No one else had the technical knowledge to continue making the go-to varnish for art conservators worldwide. Those who had stocked up used the precious liquid sparingly, dreading the day…

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#’Fool’s gold’ may be valuable after all

“#’Fool’s gold’ may be valuable after all” This image shows an example of a crystal of iron sulfide grown in the University of Minnesota lab to extremely high purity using a method called chemical vapor transport. Note the “goldish” sheen, which is characteristic of pyrite, or fool’s gold. Credit: University of Minnesota In a breakthrough…

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#Nondestructive positron beams probe damage, support safety advances in radiation environments

“#Nondestructive positron beams probe damage, support safety advances in radiation environments” A combination of positron annihilation spectroscopy and transmission electron microscopy reveals new insights into how damage is formed in irradiated materials, suggesting a mechanism in which large holes in the material absorb atoms in interstitial positions in the lattice and shrink, but leave behind…

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#How a crystalline sponge sheds water molecules

“#How a crystalline sponge sheds water molecules” A microscope image showing a porous, crystalline material called a metal-organic framework, or MOF (the material in purple). This MOF is made from cobalt(II) sulfate heptahydrate, 5-aminoisophthalic acid and 4,4′-bipyridine, and it is shown in its hydrated state. Credit: Travis Mitchell  How does water leave a sponge? In…

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#Biphilic surfaces reduce defrosting times in heat exchangers

“#Biphilic surfaces reduce defrosting times in heat exchangers” Time-lapse images of dynamic defrosting on superhydrophobic and biphilic surfaces. The time t = 0 represents the instant when melting of frost was first observed visually. Credit: Nenad Miljkovic, Grainger Engineering Ice formation and accumulation are challenging concerns for several industrial applications including heating ventilation air conditioning…

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